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Journal Home > Volume 1 , Issue 1
Energy Materials and Devices 2023, 1(1): 9370005
https://doi.org/10.26599/EMD.2023.9370005
Review | Open Access | Issue | Published: 25 September 2023


DEVELOPING ARTIFICIAL SOLID-STATE INTERPHASE FOR LI METAL ELECTRODES: RECENT
ADVANCES AND PERSPECTIVE

Show Author's Information Hide Author's Information Yanyan Wang,  Mingnan Li, 
Fuhua Yang,  Jianfeng Mao,  Zaiping Guo( )

School of Chemical Engineering and Advanced Materials, The University of
Adelaide, Adelaide, South Australia 5005, Australia
Keywords:
interfaces, artificial SEI, Li metal electrode, high-energy-density batteries

Cite this article:
Wang Y, Li M, Yang F, et al. Developing artificial solid-state interphase for Li
metal electrodes: recent advances and perspective. Energy Materials and Devices,
2023, 1(1): 9370005. https://doi.org/10.26599/EMD.2023.9370005
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Abstract Full text About this article
Abstract

The failure of Li metal anodes can be attributed to their unstable
electrode/electrolyte interface, especially the continuous formation of solid
electrolyte interphase (SEI) and dendrite growth. To address this challenge,
scholars proposed the construction of artificial SEI (ASEI) as a promising
strategy. The ASEI mainly homogenizes the distribution of Li+, mitigates
dendrite growth, facilitates Li+ diffusion, and protects the Li metal anode from
electrolyte erosion. This review comprehensively summarizes the recent progress
in the construction of ASEI layers in terms of their chemical composition.
Fundamental understanding of the mechanisms, design principles, and functions of
the main components are analyzed. We also propose future research directions to
facilitate the in-depth study of ASEI and its practical applications in Li metal
batteries. This review offers perspectives that will greatly contribute to the
design of practical Li metal electrodes.


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About this article


DEVELOPING ARTIFICIAL SOLID-STATE INTERPHASE FOR LI METAL ELECTRODES: RECENT
ADVANCES AND PERSPECTIVE

Show Author's information Hide Author's Information Yanyan Wang, Mingnan
Li, Fuhua Yang, Jianfeng Mao, Zaiping Guo( )

School of Chemical Engineering and Advanced Materials, The University of
Adelaide, Adelaide, South Australia 5005, Australia



ABSTRACT

The failure of Li metal anodes can be attributed to their unstable
electrode/electrolyte interface, especially the continuous formation of solid
electrolyte interphase (SEI) and dendrite growth. To address this challenge,
scholars proposed the construction of artificial SEI (ASEI) as a promising
strategy. The ASEI mainly homogenizes the distribution of Li+, mitigates
dendrite growth, facilitates Li+ diffusion, and protects the Li metal anode from
electrolyte erosion. This review comprehensively summarizes the recent progress
in the construction of ASEI layers in terms of their chemical composition.
Fundamental understanding of the mechanisms, design principles, and functions of
the main components are analyzed. We also propose future research directions to
facilitate the in-depth study of ASEI and its practical applications in Li metal
batteries. This review offers perspectives that will greatly contribute to the
design of practical Li metal electrodes.

Keywords: interfaces, artificial SEI, Li metal electrode, high-energy-density
batteries




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Received: 23 August 2023
Revised: 09 September 2023
Accepted: 10 September 2023
Published: 25 September 2023
Issue date: September 2023


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