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Polymers for Advanced Technologies
Volume 33, Issue 7 p. 2091-2112
REVIEW ARTICLE


STYRENE-BUTADIENE-STYRENE-BASED SHAPE MEMORY POLYMERS: EVOLUTION AND THE CURRENT
STATE OF ART


Sayan Basak, 

Sayan Basak

 * orcid.org/0000-0002-8322-4485

Department of Polymer Science & Technology, University of Calcutta, Kolkata,
West Bengal, India

Search for more papers by this author
Abhijit Bandyopadhyay, 

Corresponding Author

Abhijit Bandyopadhyay

 * abpoly@caluniv.ac.in
 * abhijitbandyopadhyay@yahoo.co.in

 * orcid.org/0000-0001-7373-947X

Department of Polymer Science & Technology, University of Calcutta, Kolkata,
West Bengal, India

Correspondence

Abhijit Bandyopadhyay, Department of Polymer Science & Technology, University of
Calcutta, 92, A.p.C Road, Kolkata 700 009, West Bengal, India.

Email: abpoly@caluniv.ac.in; abhijitbandyopadhyay@yahoo.co.in

Search for more papers by this author
Sayan Basak, 

Sayan Basak

 * orcid.org/0000-0002-8322-4485

Department of Polymer Science & Technology, University of Calcutta, Kolkata,
West Bengal, India

Search for more papers by this author
Abhijit Bandyopadhyay, 

Corresponding Author

Abhijit Bandyopadhyay

 * abpoly@caluniv.ac.in
 * abhijitbandyopadhyay@yahoo.co.in

 * orcid.org/0000-0001-7373-947X

Department of Polymer Science & Technology, University of Calcutta, Kolkata,
West Bengal, India

Correspondence

Abhijit Bandyopadhyay, Department of Polymer Science & Technology, University of
Calcutta, 92, A.p.C Road, Kolkata 700 009, West Bengal, India.

Email: abpoly@caluniv.ac.in; abhijitbandyopadhyay@yahoo.co.in

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First published: 06 April 2022
https://doi.org/10.1002/pat.5682
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ABSTRACT

Styrene butadiene styrene (SBS) block copolymers comprise of two phases
structured domains involving polystyrene “hard” domains and butadiene “soft”
domains. The styreneic domains provide a physical crosslink that enables SBS to
behave like a highly flexible thermoplastic elastomer. Recently, with the rise
of smart elastomers, SBS-based matrices are being extensively used in
transforming them into elastomers that can exhibit shape change when excited
with a range of stimuli (shape memory elastomers). With the advantages of
long-range elasticity, reprocessability, and ability to be modified into various
tailor-made shape morphing elastomers, the use SBS-based elastomers has
exceptionally risen in the scope of deployable structures temperature sensors,
snap fittings, and actuators. This review attempts to tether the recent
development in SBS-based shape memory polymers along with highlighting the
fabrication routes and the shape memory mechanistic pathway. The review
introduces the concept of shape memory polymers, classification, and their
characterization, followed by shape memory elastomers and finally one
way/two-way SBS-based shape memory elastomers. In an attempt to blend both the
scientific and the engineering realm, the narrative provides a concise overview
of SBS-based shape morphing polymers' expanding boundaries.




CONFLICT OF INTEREST

All individuals listed as authors qualify as authors and have approved the
submitted version. Their work is original and is not under consideration by any
other journal. They have permission to reproduce any previously published
material.


OPEN RESEARCH


DATA AVAILABILITY STATEMENT

Data sharing is not applicable to this article as no new data were created or
analyzed in this study.

Volume33, Issue7

July 2022

Pages 2091-2112




 * RELATED


 * INFORMATION


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